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Lead Isotope project

Lead white has been used as an artist’s pigment since antiquity. It is present in almost every painting throughout the centuries and has only recently been replaced by other white pigments. It has been possible for some years to identify trace elements contained in the lead white and to categorize the different lead isotopes. There has been little comparative research done in this area. These variations can be linked to particular locations and time periods, which would hopefully lead us to the original sources for the different lead whites. The main focus of the project will be on the use, distribution and availability of lead white to artists and artist’s suppliers in the North and South concentrating on the use of lead white in the Flemish and Italian Schools of the 17th c. with particular emphasis on the artist P. P. Rubens and his contemporaries.

The Flemish painter Pieter Paul Rubens travelled extensively during his long career as an artist. Many of his important works of art were commissioned by the great European courts and executed during his well documented travel periods. The comparison between the working technique and the choice of materials in Rubens’ studio in Antwerp and during his periods of travel abroad carries great potential to gain more insight into the studio practice of the time. Since there has been surprisingly little technical and analytical research on this important artist, we have been encouraged to further investigate and follow up our initial research:

When Rubens worked in Antwerp, did he use lead white originating from local sources or was it imported?
What would the trade routes have been?
When working abroad, did Rubens obtain his pigments locally, or did he bring along his own ma-terials from Antwerp? And again what was the source (or sources) of these pigments?
Was sometimes the pigment or generally the ore imported?

The questions raised focus not only on a particular artist’s working habits, but more specifically on the origins of the pigments (where they were mined and manufactured into pigments) and the ensu-ing trade routes. Analysis of early Rubens paintings has shown very promising results already. To complement the results originating from paintings, samples from lead mines will be analysed. The results will be compared to historical trade routes.

The results from the analysis of samples taken from paintings will be referred to as secondary source material. Primary source material will refer to samples that have been obtained from original loca-tions i.e. lead mines.

The project will focus in the second part to:

1. Continue research on secondary source materials i.e. pigments found in paintings of known artists from available collections throughout Europe and America. The research will include analysis and comparison of the lead isotope and trace elements found in samples taken from paintings of the fol-lowing schools:

  1. Southern Schools of the 17th century: Milan, Venice, Genoa, Florence and Rome and Naples
    1. Rubens and his contemporaries working in Italy
    2. Southern Artists working in the North (Gentileschi’s)
  2. Spanish Schools
    1. Rubens and his contemporaries working in Spain
  3. Northern Schools of the 17th century
    1. Collect data from Rubens and his contemporaries (i. e. Van Dyck) working in their home environment (Antwerp, etc.)
    2. Rubens and his contemporaries working in England
  4. Collect samples of primary source materials i.e. naturally occurring lead ores
    1. Collect samples from lead mines in Northern Europe
    2. Collect samples from lead mines in Southern (eastern) Europe

This project has been accepted by the Swiss National Science Foundation (Schweizerischer National-fond) and is carried out at the Laboratories of the Swiss Federal Laboratories for Materials Testing and Research (EMPA) at St. Gall. Institutions and collectors are invited to participate and to cooper-ate. This collaboration includes providing tiny samples from paintings or, giving permission to take samples. Should you know of similar data be analysed in your institution, we would be interested in contacting you. The analysis will be carried out at no costs for the contributors.
The response has been positive and the following institutions have already agreed to participate and provide samples:
Collection of HM Queen Elisabeth II
Courtauld Institute of Art, University of London
Denkmalpflege des Kantons St. Gallen
Galerie Koller, Zürich
Getty Conservation Institute, Los Angeles
Hamilton Kerr Institute, University of Cambridge
Historisches Museum St. Gallen
Institut Royal du Patrimoine Artistique, IRPA, Brüssel
Kunsthaus Zürich
Kunsthistorisches Museum, Wien
Museum of Fine Art, Boston
National Gallery of Art, Washington,
National Gallery, London
Opificio delle Pietre Dure, Florenz
Royal Cabinet of Paintings Mauritshuis, Den Haag
Rubenianum in Antwerpen
Sammlungen des Fürsten von Liechtenstein
Stedelijke Musea Antwerpen
Stiftung Sammlung E. G. Bührle, Zürich
Strauss Center for Conservation and Technical Studies, Harvard University Art Museums, Cam-bridge
Schweizerisches Landesmuseum
Technische Universität Bergakademie Freiberg
Vadiana, St. Gallen
Welti-Furrer Fine Art AG
Yale University Art Gallery, New Haven


   
 
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